Question 6.sp.3: A balloon that contains 0.50 L of air at 25 °C is cooled to ...

A balloon that contains 0.50 L of air at 25 °C is cooled to –196 °C. What volume does the balloon now occupy?
Analysis
Since this question deals with volume and temperature, Charles’s law is used to determine a final volume because three quantities are known—the initial volume and temperature (V_{1} and T_{1}), and the final temperature ( T_{2}).

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[1] Identify the known quantities and the desired quantity.

V_{1} = 0.50 L
T_{1}= 25 °C      T_{2}= –196 °C                             V_{2}= ?
known quantities                                 desired quantity

• Both temperatures must be converted to Kelvin temperatures using the equation
K = °C + 273.
T_{1}= 25 °C + 273 = 298 K
T_{2}= –196 °C + 273 = 77 K

[2] Write the equation and rearrange it to isolate the desired quantity, V_{2}, on one side.
• Use Charles’s law.

[3] Solve the problem.
• Substitute the three known quantities into the equation and solve for V_{2}.

• Since the temperature has decreased, the volume of gas must decrease as well.

 

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