Question 8.4: Acid Strength Which is the stronger acid: (a) Benzoic acid w...

Acid Strength

Which is the stronger acid:

(a) Benzoic acid with a K_{ a } \text { of } 6.5 \times 10^{-5} or hydrocyanic acid with a K_{ a } of 4.9 \times 10^{-10}?

(b) Boric acid with a p K_{ a } of 9.14 or carbonic acid with a p K_{ a } of 6.37?

Strategy

Relative acid strength is determined by comparing the K_{ a } values or the p K_{ a } values. If using K_{ a } values, the stronger acid has the larger K_{ a }. If using p K_{ a } values, the stronger acid has the smaller p K_{ a }.

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(a) Benzoic acid is the stronger acid; it has the larger p K_{ a } value.

(b) Carbonic acid is the stronger acid; it has the smaller p K_{ a }.

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