Pressurized air in an insulated rigid tank equipped with an electric heater is allowed to escape at constant temperature until the pressure inside drops to a specified value. The amount of electrical energy supplied to air is to be determined.
Assumptions 1 This is an unsteady process since the conditions within the device are changing during the process, but it can be analyzed as a uniform-flow process since the exit conditions remain constant. 2 Kinetic and potential energies are negligible. 3 The tank is insulated and thus heat transfer is negligible. 4 Air is an ideal gas with variable specific heats.
Analysis We take the contents of the tank as the system, which is a control volume since mass crosses the boundary (Fig. 5–52). Noting that the microscopic energies of flowing and nonflowing fluids are represented by enthalpy h and internal energy u, respectively, the mass and energy balances for this uniform-flow system can be expressed as
\text{Mass balance:}\quad\quad m_{\text{in}} – m_{\text{out}} = \Delta m_{\text{system}} \rightarrow m_{\text{e}} = m_{1} – m_{2}
\begin{aligned}\text{Energy balance:}\underbrace{E_{\mathrm{in}}-E_{\mathrm{out}}}_{\begin{array}{c}\text { Net energy transfer } \\\text { by heat, work, and mass }\end{array}} &=\underbrace{\Delta E_{\mathrm{system}}}_{\begin{array}{r}\text { Change in internal, kinetic, } \\\text { potential, etc., energies }\end{array}} \\{W}_{e, \text { in }}-{m}_{e}h_{e} &= m_{2}u_{2} -m_{1}u_{1}\quad \text { (since } Q \cong \mathrm{ke} \cong \mathrm{pe} \cong 0)\end{aligned}
The gas constant of air is R = 0.287 kPa·m^3/kg·K (Table A-1). The initial and final masses of air in the tank and the discharged amount are determined from the ideal gas relation to be
\begin{array}{l}m_{1}=\frac{P_{1} V_{1}}{R T_{1}}=\frac{(600 \mathrm{kPa})\left(8 \mathrm{~m}^{3}\right)}{\left(0.287 \mathrm{kPa} \cdot \mathrm{m}^{3} / \mathrm{kg} \cdot \mathrm{K}\right)(400 \mathrm{~K})}=41.81 \mathrm{~kg} \\\\m_{2}=\frac{P_{2} \mathrm{~V}_{2}}{R T_{2}}=\frac{(200 \mathrm{kPa})\left(8 \mathrm{~m}^{3}\right)}{\left(0.287 \mathrm{kPa} \cdot \mathrm{m}^{3} / \mathrm{kg} \cdot \mathrm{K}\right)(400 \mathrm{~K})}=13.94 \mathrm{~kg} \\\\m_{e}=m_{1}-m_{2}=41.81-13.94=27.87 \mathrm{~kg}\end{array}
The enthalpy and internal energy of air at 400 \mathrm{~K} are h_{e}=400.98 \mathrm{~kJ} / \mathrm{kg} and u_{1}=u_{2}= 286.16 \mathrm{~kJ} / \mathrm{kg} (Table A-17). The electrical energy supplied to air is determined from the energy balance to be
\begin{aligned}W_{e, \text { in }}=& m_{e} h_{e}+m_{2} u_{2}-m_{1} u_{1} \\=&(27.87 \mathrm{~kg})(400.98 \mathrm{~kJ} / \mathrm{kg})+(13.94 \mathrm{~kg})(286.16 \mathrm{~kJ} / \mathrm{kg}) \\&-(41.81 \mathrm{~kg})(286.16 \mathrm{~kJ} / \mathrm{kg}) \\=& 3200 \mathrm{~kJ}=0.889 \mathrm{kWh}\end{aligned}
since 1 \mathrm{kWh}=3600 \mathrm{~kJ}.
Discussion If the temperature of discharged air changes during the process, the problem can be solved with reasonable accuracy by evaluating h_{e} at the average discharge temperature T_{e}=\left(T_{2}+T_{1}\right) / 2 and treating it as constant.