Question 2.10: In the manufacture of vinyl chloride (VC) by the pyrolysis o...

In the manufacture of vinyl chloride (VC) by the pyrolysis of dichloroethane (DCE), the reactor conversion is limited to 55 per cent to reduce carbon formation, which fouls the reactor tubes.Calculate the quantity of DCE needed to produce 5000kg/h VC.

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Basis: 5000 kg/h VC (the required quantity).

Reaction: C_{2}H_{4}Cl_{2}\longrightarrow C_{2}H_{3}Cl+HCl
mol weights DCE 99, VC 62.5
kmol/h VC produced = \frac{5000}{62.5}=\underline{\underline{80} }
From the stoichiometric equation, 1 kmol DCE produces 1 kmol VC. Let X be DCE feed
kmol/h:
Per cent conversion = 55 = \frac{80}{X} \times 100
X= \frac{80}{0.55} =\underline{\underline{145.5 kmol/h} }
In this example the small loss of DCE to carbon and other products has been neglected.
All the DCE reacted has been assumed to be converted to VC.

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