In this problem we will recover the results Section 11.2.1 directly from the Hamiltonian for a charged particle in an electromagnetic field (Equation 4.188). An electromagnetic wave can be described by the potentials
H=\frac{1}{2 m}( p -q A )^{2}+q \varphi (4.188).
A =\frac{ E _{0}}{\omega} \sin ( k \cdot r -\omega t), \quad \varphi=0 .
where in order to satisfy Maxwell’s equations, the wave must be transverse \left( E _{0} \cdot k =0\right) and of course travel at the speed of light (\omega=c| k |) .
(a) Find the electric and magnetic fields for this plane wave.
(b) The Hamiltonian may be written as H^{0}+H^{\prime} where H^{0} is the Hamiltonian in the absence of the electromagnetic wave and H^{\prime} is the perturbation. Show that the perturbation is given by
\hat{H}^{\prime}(t)=\frac{e}{2 i m \omega} e^{i k \cdot r } E _{0} \cdot \hat{ p } e^{-i \omega t}-\frac{e}{2 i m \omega} e^{-i k \cdot r } E _{0} \cdot \hat{ p } e^{i \omega t} (11.127).
plus a term proportional to E_{0}^{2} that we will ignore. Note: the first term corresponds to absorption and the second to emission.
(c) In the dipole approximation we set e^{i k \cdot r } \approx 1 . With the electromagnetic wave polarized along the z direction, show that the matrix element for absorption is then
V_{b a}=-\frac{\omega_{0}}{\omega} \wp E_{0} .
Compare Equation 11.41. They’re not exactly the same; would the difference effect our calculations in Section 11.2.3 or 11.3? Why or why not? Hint: To turn the matrix element of p into a matrix element of r, you need to prove the following identity: i m\left[\hat{H}^{0}, \hat{ r }\right]=\hbar \hat{ p } .
V_{b a}=-\wp E_{0} (11.41).