Question 5.9.3: Three cylinders labelled i (where i = 1, 2, 3), each of sect...

Three cylinders labelled i (where i = 1, 2, 3), each of section A and each containing N moles of ideal gas (Fig. 5.3), are linked to a table that ensures a thermal contact between the three cylinders. The system is thus maintained at constant temperature T. The pistons, which keep the gas inside each cylinder, are mounted on a lever. The mass of the lever and the thermal transfers with this mechanical system are negligible.

1. Determine the norm F_i of the forces exerted by the ith piston on the lever.
2. Applying a principle of classical mechanics, establish the conditions on the pressure values p_i when the lever is horizontal at equilibrium.
3. Determine the relations between the infinitesimal variations of volume dV_i (i = 1, 2, 3) imposed by the lever.
4. Determine the infinitesimal variation of internal energy dU of the system during an infinitesimal motion of the lever.
5. Determine the infinitesimal variation of entropy dS of the system during an infinitesimal motion of the lever, using the equilibrium condition for the pressure in each cylinder.

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1. The N moles of gas contained in the ith cylinder satisfy the ideal gas equation of state (5.47), i.e.

pV = NR T

p_i V_i = NR T.

The norm F_i exerted on the lever by the N moles of gas contained in the ith cylinder is,

F_i=\left\|F_i\right\| =p_iA=\frac{NR TA}{V_i}.

2. The mechanical condition implied by the equilibrium is that the net torque M^{ext}_{i} with respect to the fulcrum of the lever must vanish. When the lever is horizontal, this condition implies,

\sum\limits_{i=1}^{3}{M^{ext}_i} =0 .   ⇒    (2F_1 + F_2 − 3F_3) d = 0.

Dividing this condition by Ad, we obtain a relation between the pressures in each cylinder, i.e.

 2p_1 + p_2 − 3p_3 = 0.

3. The infinitesimal variations dV_i of the volume of gas in the ith cylinder is given by,

dV_i = Adh_i .

where dh_i is the height variation and A is the cross-section of the piston. The data on the figure imply that,

dh_1 = 2dh_2      and    dh_3 = −3dh_2 .

which in turn implies that after multiplication by the cross-section A,

dV_1 = 2dV_2      and    dV_3 = −3dV_2 .

Therefore, the total volume of gas V is constant, i.e.

dV_1 + dV_2 + dV_3 = 0     and thus      V = V_1 + V_2 + V_3 = const.

4. Taking into account the extensive character of the internal energy, during an infinitesimal isothermal process (i.e. dT = 0), the internal energy variation dU_i of the gas contained in the ith cylinder vanishes. This implies that the infinitesimal internal energy variation (5.62) of the system vanishes, i.e.

U = cNRT

dU_i = cNRdT = 0 and thusdU=\sum\limits_{i=1}^{3}{dU_i} =0.

5. Taking into account the Gibbs relation (4.1) and the extensive characters of entropy and volume during an infinitesimal isothermal process associated with the motion of the lever, the infinitesimal entropy variation dS of the system is given by,

dU=TdS-pdV+\sum\limits_{A=1}^{r}{\mu _AdN_A}.

dS=\sum\limits_{i=1}^{3}{dS_i}=\sum\limits_{i=1}^{3}{\frac{p_idV_i}{T} }=NR\sum\limits_{i=1}^{3}{\frac{dV_i}{V_i} }=NR\biggl(\frac{dV_1}{V_1} +\frac{dV_2}{V_2}+\frac{dV_3}{V_3}\biggr).

Thus, we find that the energy variation of the system during an infinitesimal change in position of the lever vanishes, i.e.

dS=NR dV_2 \biggl(\frac{2}{V_1} +\frac{1}{V_2}+\frac{3}{V_3}\biggr)=\frac{dV_2}{T}\biggl(2p_1+p_2+3p_3\biggr)=0.

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