Question 15.2: What is the molarity of each ion in a solution of (a) 2.0 M ...

What is the molarity of each ion in a solution of (a) 2.0 M NaCl and (b) 0.40 M K_2SO_4 Assume complete dissociation.

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(a) According to the dissociation equation,

NaCl \xrightarrow[]{H_2O} Na^+(aq) + Cl^-(aq)

1 mol                                  1 mol                    1 mol

the concentration of Na^+ is equal to that of NaCl : 1 mol NaCl → 1 mol Na^+ and the concentration of Cl^-  is also equal to that of NaCl Therefore the concentrations of the ions in 2.0 M NaCl are 2.0 M Na^+  and 2.0 M  Cl^-

(b) According to the dissociation equation

K_2SO_4 \xrightarrow[] {H_2O} 2K^+(aq) + SO^{2-}_4(aq)

1 mol                                     2 mol                           1 mol

the concentration of K^+ is twice that of K_2SO_4 and the concentration of SO_4^{2-} is equal to that of K_2SO_4 .Therefore the concentrations of the ions in 0.40 M K_2SO_4 are 0.80 M K^+ and 0.40 M SO_4^{2-}

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