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Question 10.4: A particle of mass m and charge e confined to motion in the ......

A particle of mass m and charge e confined to motion in the x direction oscillates in a one-dimensional harmonic potential with angular frequency ω.

(a) Show, using perturbation theory, that the effect of an applied uniform electric field E in the x direction is to lower all the energy levels by e^{2}\left|E\right|^{2} /2m\omega ^{2}.

(b) Compare this with the classical result.

(c) Use perturbation theory to calculate the new ground-state wave function.

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(a) The solution follows that already given in this chapter.

(b) The new energy levels of the oscillator are to second order

E=\hbar \omega \left(n+\frac{1}{2} \right)-\frac{e^{2}\left|E\right|^{2} }{2\kappa }

which is the same as the exact result. Physically, the particle oscillates at the same frequency, ω, as the unperturbed case, but it is displaced a distance of e\left|E\right|/m\omega ^{2}, and the new energy levels are shifted by -e ^{2}\left|E\right|^{2}/ 2m\omega ^{2}.

(c) The ground-state wave function of the unperturbed harmonic oscillator is

\psi _{0}(x)=\left(\frac{m\omega }{\pi \hbar } \right)^{1/4} e^{-x^{2}m\omega /2\hbar }

After the perturbation, it is

\psi _{0}(x)=\left(\frac{m\omega }{\pi \hbar } \right)^{1/4} e^{-\frac{m\omega }{2\hbar }\left(x-\frac{e\left|E\right| }{m\omega^{2} } \right)^{2} }

The result using second-order perturbation theory is

\psi =\psi ^{(0)}_{m} +\sum\limits_{k\neq m}{\frac{W_{mk} }{E_{m}-E_{k} } \psi ^{(0)}_{k}}+\sum\limits_{k\neq m}{} \left(\left(\sum\limits_{n\neq m}{\frac{W_{kn}W_{mn} }{(E^{(0)}_{m}-E^{(0)}_{n} )(E^{(0)}_{m}-E^{(0)}_{k})} -\frac{W_{mm} W_{km} }{(E^{(0)}_{m}-E^{(0)}_{k})^{2} } } \right) \psi ^{(0)}_{k}-\frac{1}{2}\frac{\left|W_{mn} \right|^{2} }{(E^{(0)}_{m}-E^{(0)}_{n})^{2} } \psi ^{(0)}_{m} \right)

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