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Question 5.9: Silicon Device Fabrication Devices such as transistors are m......

Silicon Device Fabrication
Devices such as transistors are made by doping semiconductors. The diffusion coefficient of phosphorus in Si is D = 6.5 × 10^{-13} cm²/s at a temperature of 1100°C. Assume the source provides a surface concentration of 10^{20} atoms/cm³ and the diffusion time is one hour. Assume that the silicon wafer initially contains no P.
Calculate the depth at which the concentration of P will be 10^{18} atoms/cm³. State any assumptions you have made while solving this problem.

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We assume that we can use one of the solutions to Fick’s second law (i.e., Equation 5-7):
\frac{c_{s} \ – \ c_{x}}{c_{s} \ – \ c_{0}}= erf ( \frac{x}{2\sqrt{Dt}})       (5-7)
We will use concentrations in atoms/cm³, time in seconds, and D in \frac{cm^2}{s} . Notice that the left-hand side is dimensionless. Therefore, as long as we use concentrations in the same units for c_{s}, c_{x}, and c_{0}, it does not matter what those units are.
\frac{c_{s} \ – \ c_{x}}{c_{s} \ – \ c_{0}}=  \frac{10^{20} \ \frac{atoms}{cm^3} \ – \ 10^{18} \ \frac{atoms}{cm^3}}{10^{20} \ \frac{atoms}{cm^3} \ – \ 0 \ \frac{atoms}{cm^3}}=0.99
= erf \left[\frac{x}{2 \sqrt{(6.5 × 10^{-13} \ \frac{cm^2}{s})(3600 \ s)}} \right]
= erf \left( \frac{x}{9.67 × 10^{-5}} \right)
From the error function values in Table 5-3 (or from your calculator/computer), if erf(z) = 0.99, z = 1.82; therefore,
1.82 = \frac{x}{9.67 × 10^{-5}}
or
x = 1.76 × 10^{-4} \ cm
or
x = (1.76 × 10^{-4} \ cm)(\frac{10^4 \ μm}{cm})
x = 1.76 μm

Note that we have expressed the final answer in micrometers since this is the length scale that is appropriate for this application. The main assumptions we made are (1) the D value does not change while phosphorus gets incorporated in the silicon wafer and (2) the diffusion of P is only in one dimension (i.e., we ignore any lateral diffusion).

 

Table 5-3 Error function values for Fick’s second law
Argument of the Error Function \frac{x}{ 2 \sqrt{Dt}} Value of the Error Function erf \frac{x}{ 2 \sqrt{Dt}}
0 0
0.10 0.1125
0.20 0.2227
0.30 0.3286
0.40 0.4284
0.50 0.5205
0.60 0.6039
0.70 0.6778
0.80 0.7421
0.90 0.7969
1.00 0.8427
1.50 0.9661
2.00 0.9953

Note that error function values are available in many software packages.

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