Write down the structures of E and F. E (C11H14O2) → F + CH3CH2COO^- F →

Question

Write down the structures of E and F.

[latex] E \left( C _{11} H _{14} O _2 ight) \stackrel{ OH^-}{\longrightarrow} F + CH _3 CH _2 COO ^{-} [/latex]

[latex] \begin{matrix} F & \overset{ ext {1. }KMnO_4/OH^-}{\underset{ ext {2. }H}{\xrightarrow {\hspace{2 cm}} }} \\\\ \end{matrix} [/latex]

[IIT, 1997]

(ii) Write down the structures of G and H where G is [latex] C _4 H _8 O _3 . [/latex]

[latex] \begin{matrix} ext {Acetate} & \overset{Ac_2O}{\underset{ ext {Pyridine}}{\xleftarrow {\hspace{2 cm}} }} & ext {(G)} & \overset{NaHCO_3}{\xrightarrow {\hspace{2 cm}} } \ && \quad \quad \quad \downarrow CrO_3 \ && ext {H} \ && \quad\quad\quad \downarrow ext {Warm} \ && CH _3 COCH _3+ CO _2\end{matrix} [/latex]

[IIT, 1997]

Accepted Answer

[latex] \begin{matrix} \overset{OH^-}{\xrightarrow {\hspace{2 cm}} } \\\\\\\\ \end{matrix} [/latex]

[latex] \begin{matrix} + & CH_3CH_2COO^- \\\\\\\\\\\\\\\\\\ \end{matrix} [/latex]

[latex] \begin{matrix}CH _3 CH ( OH ) CH _2 COOH & \overset{(CH_3CO)_2O}{\underset{ ext {Pyridine}}{\xrightarrow {\hspace{2 cm}} }} & CH _3 CHCH _2 COOH \ ext {(G)} && |\ && \quad \quad \quad\quad O - C - CH _3 \ && \quad\quad\quad \quad || \ \ \ \ \ \ && \quad\quad\quad\quad O \ \ \ \ \ \end{matrix} [/latex]

[latex] \begin{matrix}CH _3 CH ( OH ) CH _2 COOH & \overset{NaHCO_3}{\xrightarrow {\hspace{2 cm}} } & CO_2 \ ext {(G)}\end{matrix} [/latex]

[latex] \begin{matrix}CH _3 CH ( OH ) CH _2 COOH & \overset{CrO_3}{\xrightarrow {\hspace{2 cm}} } & CH _3 CHCH _2 COOH & \stackrel{ \Delta}{\longrightarrow} & CH _3 COCH _3+ CO _2 \ ext {(G)} && ext {(H)}\end{matrix} [/latex]

Question 7.SSE.14: Write down the structures of E and F. E (C11H14O2) → F + CH3......

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