Question 6.4: Calculating the Heat of Reaction from the Stoichiometry How ...
Calculating the Heat of Reaction from the Stoichiometry
How much heat is evolved when 9.07 × 10^5 g of ammonia is produced according to the following equation? (Assume that the reaction occurs at constant pressure.)
N_2(g) + 3H_2(g) → 2NH_3(g); ΔH = -91.8 kJPROBLEM STRATEGY
The calculation involves converting grams of NH_3 to moles of NH_3 and then to kilojoules of heat.
Grams of NH_3 → moles of NH_3 → kilojoules of heat
You obtain the conversion factor for the second step from the thermochemical equation, which says that the production of 2 mol NH_3 is accompanied by q_p = -91.8 kJ.
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9.07 \times 10^5 \cancel{g NH _3} \times \frac{1 \cancel{mol NH _3}}{17.0 \cancel{g NH _3}} \times \frac{-91.8 kJ }{2 \cancel{mol NH _3}} = -2.45 \times 10^6 kJ
Thus, 2.45 \times 10^6 kJ \text { of heat evolves. }
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