Question 16.4: Using ΔG°f values from Appendix 1, calculate the standard fr...

Using ΔG°_{f} values from Appendix 1, calculate the standard free energy change at 25°C for the reaction referred to in Example 16.3.

ANALYSIS
equation for the reaction (CaSO_{4}(s)  →  Ca^{2+}(aq)  +  SO_{4}^{2-}(aq)) Information given:
 ΔG°_{f} values (Appendix 1) Information implied
ΔG° Asked for

STRATEGY

Obtain ΔG°_{f} values from Appendix 1 and substitute into Equation 16.3.

ΔG°_{reaction} = ∑ΔG°_{f  products} – Σ ΔG°_{f  reactants}                                       (16.3)

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ΔG° = ΔG°_{f}Ca^{2+}(aq)  +  ΔG°_{f} SO_{4}^{2-}(aq)  –  ΔG°_{f}  CaSO_{4}(s)

= -553.6 kJ – 744.5 kJ + 1321.8 kJ = +23.7 kJ

ΔG°

END POINT

Notice that the value of ΔG° at 25°C is essentially identical to that obtained in Example 16.3, which is reassuring.

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