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Question 8.2.4: Draw all resonance structures for the carbonate ion, CO3^2−....

Draw all resonance structures for the carbonate ion, CO_{3}^{2−}.

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You are asked to draw all resonance structures for a molecule or ion.
You are given the chemical formula for the molecule or ion.
The incomplete Lewis structure (octet rule not satisfied for carbon) is

\left[\begin{matrix} \,\,\,\, :\overset{..}{\underset{|}{O}}: \\:\overset{..}{\underset{..}{O}}- C- \overset{..}{\underset{..}{O}:} \end{matrix} \right] ^{2-}

The electron deficiency for carbon is corrected by changing a lone pair on an adjacent oxygen into a bonding pair. There are three oxygen atoms with lone pairs that can correct the carbon electron deficiency, so there are three equivalent resonance structures for the carbonate ion.

\left[\begin{matrix} \,\,\,\, :\overset{..}{\underset{|}{O}}: \\ \, \,\,\,\,\,\overset{..}{\underset{..}{O}}= C- \overset{..}{\underset{..}{O}:} \end{matrix} \right] ^{2-} \longleftrightarrow \left[\begin{matrix} \,\,\,\, :{\underset{||}{O}}: \\ \,\,\,\,\overset{..}{:\underset{..}{O}}- C- \overset{..}{\underset{..}{O}:} \end{matrix} \right] ^{2-}\longleftrightarrow \left[\begin{matrix} \,\,\,\, :\overset{..}{\underset{|}{O}}: \\ \,\,\overset{..}{:\underset{..}{O}}- C= \overset{..}{\underset{..}{O}} \end{matrix} \right] ^{2-}

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