Draw all resonance structures for the carbonate ion, CO_{3}^{2−}.
You are asked to draw all resonance structures for a molecule or ion.
You are given the chemical formula for the molecule or ion.
The incomplete Lewis structure (octet rule not satisfied for carbon) is
The electron deficiency for carbon is corrected by changing a lone pair on an adjacent oxygen into a bonding pair. There are three oxygen atoms with lone pairs that can correct the carbon electron deficiency, so there are three equivalent resonance structures for the carbonate ion.
\left[\begin{matrix} \,\,\,\, :\overset{..}{\underset{|}{O}}: \\ \, \,\,\,\,\,\overset{..}{\underset{..}{O}}= C- \overset{..}{\underset{..}{O}:} \end{matrix} \right] ^{2-} \longleftrightarrow \left[\begin{matrix} \,\,\,\, :{\underset{||}{O}}: \\ \,\,\,\,\overset{..}{:\underset{..}{O}}- C- \overset{..}{\underset{..}{O}:} \end{matrix} \right] ^{2-}\longleftrightarrow \left[\begin{matrix} \,\,\,\, :\overset{..}{\underset{|}{O}}: \\ \,\,\overset{..}{:\underset{..}{O}}- C= \overset{..}{\underset{..}{O}} \end{matrix} \right] ^{2-}