Electronic Polarization in Copper
Suppose that the average displacement of the electrons relative to the nucleus in a copper atom is 10^{-8} Å when an electric field is imposed on a copper plate. Calculate the electronic polarization.
The atomic number of copper is 29, so there are 29 electrons in each copper atom. The lattice parameter of copper is 3.6151 Å. Thus,
z = \frac{(4 \ \text{atoms}/\text{cell})(29 \ \text{electrons/atom})}{(3.6151 × 10^{-10} m)^3/\text{cell}} = 2.455 × 10^{30} \text{electrons}/m^3
P = zqd = (12.455 × 10^{30} \ \frac{\text{electrons}}{m^3}) (1.6 × 10^{-19} \ \frac{C}{\text{electron}})(10^{-8} Å)(10^{-10} \ m /Å)
= 3.93 × 10^{-7} C/m^2