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Question 24.3: Predicting the Mode of Nuclear Decay Problem Use the atomic ......

Predicting the Mode of Nuclear Decay

Problem Use the atomic mass of the element to predict the mode(s) of decay of the following radioactive nuclides: (a)  _5^{12}B; (b)  _{92}^{234}U; (c)  _{33}^{81}As; (d)  _{57}^{127}La.

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Plan If the nuclide is too heavy to be stable (Z > 83), it undergoes α decay. For other cases, we use the Z value to obtain the atomic mass from the periodic table. If the mass number of the nuclide is higher than the atomic mass, the nuclide has too many neutrons: N too high ⇒ β^− decay. If the mass number is lower than the atomic mass, the nuclide has too many protons: Z too high ⇒ β^+ emission and/or e^− capture.

Solution (a) This nuclide has Z = 5, which is boron (B), and the atomic mass is 10.81. The nuclide’s A value of 12 is significantly higher than its atomic mass, so this nuclide is neutron rich. It will probably undergo β^− decay.
(b) This nuclide has Z = 92, so it will undergo α decay and decrease its total mass.
(c) This nuclide has Z = 33, which is arsenic (As), and the atomic mass is 74.92. The A value of 81 is much higher, so this nuclide is neutron rich and will probably undergo β^− decay.
(d) This nuclide has Z = 57, which is lanthanum (La), and the atomic mass is 138.9. The A value of 127 is much lower, so this nuclide is proton rich and will probably undergo β^+ emission and/or e^− capture.

Check To confirm our predictions in parts (a), (c), and (d), let’s compare each nuclide’s N/Z ratio to those in the band of stability: (a) This nuclide has N = 7 and Z = 5, so N/Z = 1.40, which is too high for this region of the band, so it will undergo β^− decay. (c) This nuclide has N = 48 and Z = 33, so N/Z = 1.45, which is too high for this region of the band, so it will undergo β^− decay. (d) This nuclide has N = 70 and Z = 57, so N/Z = 1.23, which is too low for this region of the band, so it will undergo β^+ emission and/or e^− capture. Our predictions based on N/Z values were the same as those based on atomic mass.

Comment Both possible modes of decay are observed for the nuclide in part (d).

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