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Question 18.4: Name the following alkane. CH3CH2CHCH2CH2CH3...

Name the following alkane.

CH_3CH_2\underset{\underset{\underset{\underset{CH_3}{|}}{CH_2}}{|}}{C}HCH_2CH_2CH_3
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This compound has six carbon atoms in its longest continuous chain.

CH_3CH_2\underset{\underset{\underset{\underset{CH_3}{|}}{CH_2}}{|}}{C}HCH_2CH_2CH_3

The correct prefix from Table 18.3 is hex-. The base name is hexane.

This compound has one substituent named ethyl.

The base chain is numbered as follows:

\overset{1}{C}H_3\overset{2}{C}H_2\underset{\underset{\underset{\underset{CH_3}{|}}{CH_2}}{|}}{\overset{3}{C}}H\overset{4}{C}H_2\overset{5}{C}H_2\overset{6}{C}H_3

The ethyl substituent is assigned the number 3.

The name of this compound is:
3-ethylhexane

18.4
TABLE 18.3 Prefixes for Base Names of Alkane Chains
Number of Carbon Atoms Prefix
1 meth-
2 eth-
3 prop-
4 but-
5 pent-
6 hex-
7 hept-
8 oct-
9 non-
10 dec-

 

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