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Question 18.5: Name the following alkane. CH3CHCH2CHCH2CH2CH3...

Name the following alkane.

CH_3\underset{\underset{CH_3}|}CHCH_2\underset{\underset{CH_2CH_3}|}CHCH_2CH_2CH_3
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This compound has seven carbon atoms in its longest continuous chain.

CH_3\underset{\underset{CH_3}|}CHCH_2\underset{\underset{CH_2CH_3}|}CHCH_2CH_2CH_3

The correct prefix from Table 18.3 is hept-. The base name is heptane.

This compound has one substituent named methyl and one named ethyl.

The base chain is numbered as follows:

\overset{1}CH_3\underset{\underset{CH_3}|}{\overset{2}C}H\overset{3}CH_2\underset{\underset{CH_2CH_3}|}{\overset{4}C}H\overset{5}CH_2\overset{6}CH_2\overset{7}CH_3

The methyl substituent is assigned the number 2, and the ethyl substituent is assigned the number 4.

The name of this compound is:
4-ethyl-2-methylheptane
Ethyl is listed before methyl because substituents are listed in alphabetical order.

18.5
TABLE 18.3 Prefixes for Base Names of Alkane Chains
Number of Carbon Atoms Prefix
1 meth-
2 eth-
3 prop-
4 but-
5 pent-
6 hex-
7 hept-
8 oct-
9 non-
10 dec-

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