A sample of gas has an initial volume of 2.4 L at a pressure of 855 mm Hg and a temperature of 298 K. If the gas is heated to a temperature of 387 K and expanded to a volume of 4.1 L, what is its final pressure in millimeters of mercury?
GIVEN:
P_1 = 855 mm Hg
V_1 = 2.4 L
T_1 = 298 K
V_2 = 4.1 L
T_2 = 387 K
FIND: P_2
RELATIONSHIPS USED
\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2} (Combined gas law, Section 11.6)
\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}\\ P_2=\frac{P_1V_1T_2}{T_1V_2}\\=\frac{855 mm Hg\times 2.4 \cancel{L}\times 387 \cancel{K}}{298 \cancel{K} \times 4.1 \cancel{L}} \\ =6.5 \times 10^2 mm HgThe units, mm Hg, are correct. The value of the answer makes sense because the volume increase was proportionally more than the temperature decrease; therefore you would expect the pressure to decrease.