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Question 11.15: A sample of gas has an initial volume of 2.4 L at a pressure......

A sample of gas has an initial volume of 2.4 L at a pressure of 855 mm Hg and a temperature of 298 K. If the gas is heated to a temperature of 387 K and expanded to a volume of 4.1 L, what is its final pressure in millimeters of mercury?

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GIVEN:

P_1 = 855 mm Hg

V_1 = 2.4 L

T_1 = 298 K

V_2 = 4.1 L

T_2 = 387 K

FIND: P_2

RELATIONSHIPS USED

\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2} (Combined gas law, Section 11.6)

\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}\\ P_2=\frac{P_1V_1T_2}{T_1V_2}\\=\frac{855  mm  Hg\times 2.4  \cancel{L}\times 387  \cancel{K}}{298  \cancel{K} \times 4.1  \cancel{L}} \\ =6.5 \times 10^2  mm  Hg

The units, mm Hg, are correct. The value of the answer makes sense because the volume increase was proportionally more than the temperature decrease; therefore you would expect the pressure to decrease.

11.15

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