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Question 11.16: Calculate the pressure exerted by 1.2 mol of gas in a volume......

Calculate the pressure exerted by 1.2 mol of gas in a volume of 28.2 L and at a temperature of 334 K.

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GIVEN:

n = 1.2 mol

V = 28.2 L

T = 334 K

FIND: P

RELATIONSHIPS USED

PV = nRT (Ideal gas law, Section 11.8)

PV = nRT

P =\frac{nRT}{V} \\ =\frac{1.2  \cancel{mol}\times 0.0821 \frac{\cancel{L} \cdot  atm}{\cancel{mol}  \cdot  \cancel{K}}\times 334  \cancel{K}}{28.2  \cancel{L}} \\ =1.2  atm

The units (atm) are correct units for pressure. The value of the answer is a bit more difficult to judge. However, knowing that at standard temperature and pressure (T = 0 °C or 273.15 K and P = 1 atm), 1 mol of gas occupies 22.4 L, we can see that the answer is reasonable because we have a bit more than one mole of a gas at a temperature not too far from standard temperature. The volume of the gas is a bit higher than 22.4 L; therefore we might expect the pressure to be a bit higher than 1 atm.

sol 11.16

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